Product ID:N-3509 RED TREE MARKING
MSDS Date:06/04/1990
FSC:8010
NIIN:01-274-2564
MSDS Number: BHXHM

NILES CHEMICAL PAINT CO.

225 FORT STREET
NILES, MI 49120
US

Emergency Phone: 616-683-3377

Info Phone: 219-236-5856

Preparer: MIKE LICHATOWICH

Cage: 02388

NILES CHEMICAL PAINT

307 NILES, MI 49120 US

Telephone: 616-683-3377/219-236-5856

Cage: 02388

STODDARD SOLVENT

CAS: 8052-41-3

RTECS: WJ8925000

Fraction By Weight: 54%

OSHA PEL 500 PPM

ACGIH TLV: 100 PPM; 9293

ALKYD RESIN

Fraction By Weight: 21%

COBALT (SARA III)

CAS: 7440-48-4

RTECS: GF8750000

Fraction By Weight: <1%

OSHA PEL 0.1 MG/M3;AS CO

ACGIH TLV: 0.05 MG/M3;DUST 9293

MANGANESE (SARA III)

CAS: 7439-96-5

RTECS: OO9275000

Fraction By Weight: <1%

OSHA PEL (C) 5 MG/M3 DUST

ACGIH TLV: 5 MG/M3 DUST 9293

MANUFACTURER STATES UNIDENTIFIED INGREDIENTS ARE NOT

RTECS: 9999999ZZ

VOC. 4.44 LBS/GAL.

RTECS: 9999999VO

Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: SEVERE IRRITATION, LACRIMATION,
BLURRED VISION, REDNESS. SKIN: REDNESS & IRRITATION, DEFATTING
LEADING TO DERMATITIS. INHALED: NASAL & RESPIRATORY IRRITATION, CNS
DEPRESSION, VERTIGO, POSSIBLE U NCONSCIOUS, EVEN ASPHYXIATION. IF
SWALLOWED: GASTROINTESTINAL IRRITATION & ABDOMINAL PAIN, NAUSEA,
VOMITING & DIARRHEA.
Explanation of Carcinogenicity:NOT LISTED BY NTP, IARC OR OSHA.
Effects of Overexposure:EYES: SEVERE IRRIT, REDNESS, BLURRED VISION.
SKIN: REDNESS, IRRIT & DEFATTING OF SKIN. INHALED: NASAL &
RESPIRATORY IRRIT, DIZZINESS, DROWSINESS, WEAKNESS, FATIGUE,
CONFUSION, NAUSEA, HEADACHE, VERTIG O, UNCONSCIOUSNESS, EVEN
ASPHYXIATION. SWALLOWED: GASTROINTEST IRRITATION, ABDOMINAL PAIN,
NAUSEA, VOMITING & DIARRHEA
Medical Cond Aggravated by Exposure:NONE KNOWN. TARGET ORGANS: SKIN,
EYES, RESPIRATORY SYSTEM AND CNS.

First Aid:INHALE:MOVE TO FRESH AIR IMMED, GIVE CPR IF NEEDED. GET MED
ATTN IMMED. SKIN:IMMED FLUSH W/WTR. IF PENETRATES CLOTHES IMMED
REMOVE CONTAM CLOTHES & FLUSH W/WTR. GET MED ATTN. EYES:IMMED FLUSH
W/LRG AM TS OF WTR 15 MINS, LIFTING LIDS. GET MED ATTN. DO NOT WEAR
CONTACTS WHEN WORKING W/MATERIAL. SWALLOW:DRINK 1 OR 2 GLASS WTR.
DO NOT INDUCE VOMIT. CONSULT PHYSICIAN/PCC IMMED. TREAT
SYMPTOMATICALLY.

Flash Point Method:TCC
Flash Point:85 F/29 C
Lower Limits:0.8
Upper Limits:0
Extinguishing Media:DRY CHEMICAL, FOAM, CO2.
Fire Fighting Procedures:WEAR SCBA W/FULL FACEPIECE-POSITIVE PRESS MODE
& FULL PROTECT CLOTHES. USE WTR TO COOL CLOSED CONTAINER, PREVENT
PRESS BUILD-UP/AUTO-IGNITE/EXPLOSION FROM HEAT
Unusual Fire/Explosion Hazard:KEEP CONTAINER TIGHTLY CLOSED. VAPORS MAY
TRAVEL ON GROUND TO IGNITE SOURCE. ISOLATE FROM HEAT, SPARKS, ELEC
EQUIP, OPEN FLAME. CLOSED MAY EXPLODE FROM EXTREME*

Spill Release Procedures:SMALL SPILL:ELIM ALL IGNITE SOURCES. AVOID
INHALE OF VAPORS/SKIN CONTACT. USE INERT ABSORB(CLAY,SOIL)SHOVEL
RECLAIMED LIQ/ABSORB INTO RECOVERY/SALVAGE DRUMS. LARGE SPILL:SAME
AS ABOVE. ALSO DIKE TO PR EVENT FURTHER MOVEMENT, RECLAIM INTO
DRUMS/DISPOSE

Handling and Storage Precautions:AVOID STORAGE IN HIGH TEMPERATURE
AREAS OR NEAR FIRE OR OPEN FLAME. KEEP CONTAINERS CLOSED WHEN NOT
IN USE. AVOID ROUGH HANDLING.
Other Precautions:CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN
EMPTY. DO NOT WELD OR FLAME CUT ON EMPTY DRUMS.

Respiratory Protection:WEAR APPROPRIATE(TY TC-23C-75)PROPERLY FITTED
HALF-MASK OR FULL FACEPIECE RESPIRATOR (NIOSH/MSHA) DURING & AFTER
APPLICATION UNLESS AIR MONITOR DEMONSTRATES VAPOR/MIST LEVEL BELOW
APPLICABLE LIMITS.FO LLOW RESPIRATOR MFR'S DIRECTIONS FOR USE
Ventilation:VENT IN VOL/PATTERN TO KEEP AIR CONCENTRATE BELOW CURRENT
APPLICABLE OSHA PEL/TLV LIMIT & REMOVE DECOMP PRODUCTS FORMED
Protective Gloves:CHEMICAL RESISTANT (NITRILE OR VITON)
Eye Protection:CHEM GOGGLES/SAFETY GLASSES/FACE SHIELDS
Other Protective Equipment:WEAR CHEMICAL RESISTANT (NITRILE OR VITON)
CLOTHING AS NEEDED TO PREVENT SKIN CONTACT. WHEN BAKING, VENT
FUMES.
Work Hygienic Practices:WASH HANDS BEFORE EATING, SMOKING OR USING
RESTROOMS. WASH CLOTHING & DECONTAMINATE SHOES BEFORE REUSE.
Supplemental Safety and Health
EMPLOYEES SHOULD WASH PROMPTLY WHEN SKIN BECOMES CONTAMINATED. REMOVE
ANY CLOTHING THAT BECOMES WET (TO AVOID FLAMMABILITY HAZARD) AND
WASH BEFORE REUSE.

Boiling Pt:B.P. Text:285 TO 330F
Decomp Temp:Decomp Text:N/E
Vapor Density:> THAN AIR
Viscosity:19 Z#2
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:SLIGHT
Appearance and Odor:LIQUID, ODOR OF SOLVENTS.
Percent Volatiles by Volume:69.78

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:HIGH TEMP, SHOCK FROM DROPPING. (THIS
MATERIAL HAS BEEN FOUND TO BE STABLE UNDER REASONABLE CONDITIONS OF
STORAGE & USE)
Hazardous Decomposition Products:CAN PRODUCE CARBON MONOXIDE AND/OR
CARBON DIOXIDE.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH APPLICABLE LOCAL,
STATE AND FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.